I think it would be difficult to argue that a failed A/C compressor might lead to a catastrophic battery thermal event because an i3 automatically reduces the battery pack's power output when its temperature increases above a certain limit. Reduced power output would reduce battery pack heating. If it gets hot enough, its output power would probably be stopped so that further heating wouldn't occur.
So I don't think that a failed compressor is dangerous other than it could eventually leave one stranded. However, it's a poor design that a compressor that fails by imploding could total an i3 due to the high repair cost. Do A/C compressors implode regularly in other vehicles? Maybe the i3 compressor design is faulty or its quality, low.