I'm a fairly new i3 Rex owner, and brand new here!
My daily round trip commute is similar, being about 50 miles of A road including a 10 mile stretch of Motorway. I don't drive slowly, and cruise at about 75mph on the motorway part. Mine is the 60Ah version, and I usually arrive home with anywhere between 25 and 40% left in the battery, dependent on if I popped out to the local service station for a sandwich at lunch or not, and what sort of speed either side of the motorway I've averaged. 50-55 on the A and B roads is about right though, on average.
The caveat is, this is during the summer with high ambient temps. In the winter I expect it will be a much closer call, and realistic range on mine with a full battery in 0-5c will likely be 60 miles.
If you're buying the 94Ah version though, I expect you'll breeze it any time of the year and with any load on the vehicle.
I've downloaded the free Apple Book 'Electric Vehicles and the BMW i3' by David Bricknell and there are a couple of graphs in there that show energy consumption of 60Ah/94Ah versions at various speeds and temperatures. It seems to suggest around 55-60 for the 60Ah and approx 90-95 for the 94Ah. That's summer though, it will drop in the winter. That's also assuming a theoretical 75mph all the time with no changes in elevation or head or tail winds though. In reality, you'll be stopping and starting either side of a motorway stint which will extend range significantly, as will backing off to 70mph instead of 75. The 94Ah version seems to be happier at prolonged high speed than the 60Ah version too, all to do with discharge rates of the different sized packs.
I'm averaging 4.2 miles per kWh, which multiplied by 18.8kwh (my 60Ah cars available power) equals a theoretical 78 miles. That is in summer though don't forget. If I had the 94Ah version, I'd probably be looking at a practical range of 110-115 at the same consumption?
Sorry to go on, but it sounds like this deliberation is something that everybody has when they first ask themselves the question 'would a BMW i3 work for me'!
I needed another option for occasional longer trips, but didn't fancy another car, so hence the Rex, but it's usually silent in the back as I see it as a backup.