On my boat I had a bank of 2v batteries (12 to yield 24v) that would deliver 100a for 10hrs = 24,000kWh
You wish! It's actually 24kWh.
Other contributors to this thread have been getting confused between
rates of discharge and
capacity.
A battery - any battery - has a
capacity. It may be measured in milli-Ampere-hours (mAh) for small batteries, and Ampere-hours (Ah) for bigger ones. It's a measure of how much electrical energy can be stored (or delivered by) it.
Lead-acid batteries in particular are almost always specified at a
rate of discharge of either a 10-hour or 20-hour rate. If 10-hour rate, the stated capacity will be delivered if it is discharged at 1/10 of the Ah capacity. And so a 20 hour rate 100Ah battery would deliver 100/20 = 5Amps for 20 hours before it was discharged. They can deliver more current if needed (hundreds of Amps for engine starting, for example), but the amount of charge available at high rates is limited.
Lithium-ion batteries suffer much less from rate limitations than Lead-acid batteries and a discharge rate is not normally specified. It's feasible to discharge them quickly if needed.
Turning to the rates of discharge issue, there is also confusion between power and current. In the i3, it's usual to discuss power - which is a rate of discharge. So, for example, cruising at a
steady 70mph, you might be using perhaps 18kW continuously - and so you'd use all the available charge in an hour (18kW*1hr = 18kWh), and have travelled 70 miles doing so. There is no current measurement available in the car, but we can calculate that at full power (125kW) over 300Amps are being drawn from the 400Volt battery! (It's a good thing that you can't actually
use 125kW for long, because if you could, the battery would be flat in less than ten minutes.)
BrianStanier is correct, but didn't make clear that the "headroom" in capacity between 22 and 18.8kWh is shared between the fully-charged state and the fully discharged ends of the battery's capacity. It's important to have a bit of headroom near full charge so there is somewhere to "put" regenerated energy if necessary, and at the bottom it's important not to fully discharge the battery to avoid damaging it.