What you are describing is the hidden menu accessible on the i3 instrument panel which is apparently shared by several BMW models. The fuel tank menu items don't seem to apply to an i3. However, I've owned only BEV's, so maybe they're applicable to a REx.
It would be unusual for the previous owner to have enabled HSOC but without increasing the available fuel capacity. A 91 mile gasoline range seems higher than normal. It was supposed to be no greater than the electric range which was 72 miles as rated by the E.P.A.
You could run the REx engine until it runs out of fuel and then pay attention to how much fuel the tank will take until the fuel nozzle clicks off. Don't continue adding fuel after the nozzle clicks off because you could "overfill" the tank such that liquid gasoline enters the activated charcoal gasoline vapor trap which could cause problems. I don't recall the restricted North American fuel tank capacity (1.9 gal.?). It might be as high as 2.4 gal. after the software-limited fuel tank capacity has been increased.
Alternatively, you could license the BimmerCode app (<$50) which would show you the current the fuel tank capacity in liters and allow you to increase it if it's still software-limited. You'd also need to buy an OBD to either WiFi or Bluetooth adapter (~$30 at Amazon) to wirelessly connect your smartphone to the OBD port. BimmerCode can change the behavior of many features, so many including me find its purchase very worthwhile.